Air Liquide offers seven distinct product classes. One product class that offers product and specification customization is our Custom Class™ gas mixtures.
- These custom-engineered specialty gas mixtures can be produced to any level of certification you require, including dual-analyzed, dual-certified and single-certified.
- Air Liquide has a wide variety of components available for blending. We are also able to blend customer-supplied proprietary components.
- As you define the specialty gas or liquid mixture required, we can work with you to advise you on the type of traceability available.
- Air Liquide’s custom gas and liquid mixtures are available in a full line of refillable and transportable containers. Transportable cylinders are available for small volume applications or where container portability is necessary. Recommendations for use of steel, aluminum or other specialized cylinders are made in the interest of maximizing mixture stability and utility.
- Every analyzed Custom Class gas mixture is shipped with a Certificate of Accuracy. This customized document provides detailed product information, including special handling instructions and component information.
For more information about our custom specialty gas products, please contact us via email, request a quote or call our Solutions Center at 877.715.8651. Our highly trained representatives can provide expert assistance with technical issues as well as quick responses about quotes for custom products or grades not shown on this website.
Most SCOTT™ gas mixtures from Air Liquide America Specialty Gases can be NIST-traceable either directly or by weight. Direct NIST-traceability is achieved by laboratory analysis of your gas mixture on an instrument directly calibrated with gas reference material from NIST such as an SRM (Standard Reference Material) or NTRM (NIST-Traceable Reference Material). Using a GMIS (Gas Manufacturer's Intermediate Standard) to calibrate an instrument results in traceability but it is no longer directly traceable.
NIST-traceable by weight applies to process traceability rather than analytical traceability. In order to have process traceability, the blending method used for your gas mixture must also be directly calibrated with reference material from NIST. For example, if a gravimetric blending scale is calibrated with NIST Class 1 Weights or the older NIST Class S Weights, the resulting product is said to be "NIST-traceable by weight."
For more information, please contact us via email or call our Solutions Center at 877.715.8651.
A flam-ox gas mixture is one that contains a flammable component such as methane and an oxidizer component such as air. Depending on the concentrations involved, there may be pressure restrictions placed on the mixture so that an explosion would be contained by the gas cylinder.
For more information, please contact us via email or call our Solutions Center at 877.715.8651.
Air Liquide America Specialty Gases follows the guidelines of the Compressed Gas Association (CGA) when determining which valve to use for a particular gas mixture. The guidelines were developed primarily to prevent the intermingling of incompatible gases such as flammables and oxidizers or acids and bases. The valve outlet connection type is determined by the FTSC code for each component. This is a four-digit code consisting of four ratings: fire potential, toxicity, state of gas, and corrosiveness.
For more information, please contact us via email or call our Solutions Center at 877.715.8651.
Air Liquide America Specialty Gases uses a wide variety of instrumentation and wet chemistry methods to analyze our gas mixtures. The method used is dependent on the components of the gas mixture, the concentrations of those components, and the blend and analytical requirements.
For more information, please contact us via email or call our Solutions Center at 877.715.8651.
An accuracy of ±2% means that the reported concentration is within 2% of the true concentration of the product.
For more information, please contact us via email or call our Solutions Center at 877.715.8651.
Using the Ideal Gas Law (PV=nRT) as the starting point, it is fairly simple to calculate the cylinder content. To find the volume of gas available from a compressed gas cylinder, we apply the Ideal Gas Law (PV = nRT). In a high-pressure cylinder, the volume will be affected by the content's compressibility factor Z (PV = ZnRT). For example, a 30AL cylinder of pure helium may contain 134 cu. ft. of gas while the same cylinder of pure air may contain 144 cu. ft. under the same conditions. For these practical calculations, however, we assume ideal gas behavior for simplicity.
The Ideal Gas Law PV = nRT
Where:
P is pressure
V is volume
n is the number of moles
R is the gas constant
T is the absolute temperature
When the temperature is kept constant, we can derive the equation:
P (1) x V (1) = P (2) x V (2)
Where:
P (1) is the pressure of the compressed gas in the cylinder (psi)
V (1) is the internal volume of the cylinder, often referred to as water volume (liter)*
P (2) is the atmospheric pressure (1 atm - 14.7 psi)
V (2) is the volume of gas at pressure P (2) (liter).
Example: a 30AL sized cylinder is filled with nitrogen at 2000 psi. What is the gas volume of nitrogen from the cylinder?
P (1) is 2000 psi
V (1) is the internal volume of 30AL cylinder 29.5 liter*
P (2) is 14.7 psi
V (2) is the unknown volume of gas
Solving the equation above for V (2) gives:
V (2) = [p (1) x V (1)]/P (2) = (2000 psi x 29.5 liters)/14.7 psi = 4013 liters (approximately 140 cu. ft.)
* Click here to find the water volume of all Air Liquide high-pressure cylinders.
For more information, please contact us via email or call our Solutions Center at 877.715.8651.
Air Liquide uses mole concentrations unless otherwise requested for specialty gas mixtures.
For more information, please contact us via email or call our Solutions Center at 877.715.8651.
Blend tolerance is the difference between the blended concentration and the requested concentration. Blend accuracy is the difference between the measured value and the true value. It is calculated by taking the root mean square of the uncertainties.
For more information, please contact us via email or call our Solutions Center at 877.715.8651.
Vapor pressure is the pressure exerted when a solid or liquid is in equilibrium with its own vapor at a particular temperature. Air Liquide typically uses the vapor pressure of each minor specialty gas component at 32°F (0°C) to calculate any vapor pressure restriction of the specialty gas mixture.
For more information, please contact us via email or call our Solutions Center at 877.715.8651.
Example:
Given a 100 ppm (mole basis) gas mixture of Compound A in nitrogen, how much of Compound A will be contained in a 1 liter volume?
Key Assumptions:
- Temperature of sample is assumed to be at 21.1°C (70°F).
- Pressure of sample is assumed to be 1 atm just before injection. At around atmospheric pressure, gases behave in close to ideal manner.
Calculation:
Using the Ideal Gas Law (PV = nRT) for a temperature of 294.1°K (21.1°C), a pressure of 1 atm, and the gas constant R of 0.0821 liter x atm/mole x degree K, we find that 1 mole of ideal gas occupies 24.15 liters.
One liter of gas will then contain (1/24.15 ) moles. Since the concentration of Compound A is 100 ppm, the total number of moles of Compound A in 1 liter is (total # moles per liter) x (concentration of Compound A).
The concentration of 100 ppm (parts per million) is unit-less, and equals 100 mole-parts per 1,000,000 total moles = 0.000100 in decimal form; thus the amount of moles of Compound A in one liter of mixture is:
(1/24.15) moles per liter x 0.000100 = 0.000004 moles of Compound A per liter
In order to find the weight of Compound A, we need to know its molecular weight. For example, if Compound A is hydrogen sulfide, with a molecular weight of 34.08 gram/mole, we obtain the following concentration:
0.000004 moles per liter x 34.08 gram per mole = 0.000140 gram per liter or 0.140 milligram per liter
General Formula for Conversion of ppm (mole) to gram/liter for Gas Mixture:
(for temperature 21.1°C (70°F) and pressure 1 atm)
{Concentration (decimal form) x mole-weight (gram/mole)} of Comp. A/24.15 liter/mole = Concentration of Comp. A in g/l
Conversion of gram/liter to ppm (mole basis) for Gas Mixture:
(for temperature 21.1°C (70°F) and pressure 1 atm)
Concentration of Comp. A in gram or liter x 24.15 liter or mole/Mole-Weight of Comp. A in gram/mole = Concentration of Comp. A in decimal form
The concentration expressed in decimal form is unit-less. To find the concentration of Compound A in ppm, multiply the answer from equation above with 1,000,000. For example, a concentration of Compound A of 0.000100 (decimal form from equation above) would be 100 ppm, while a concentration of 0.010000 would be 10,000 ppm or 1%.
For more information, please contact us via email or call our Solutions Center at 877.715.8651.